沈美华博士课题组在Oranic Letters发表研究论文

发布时间:2017-07-08浏览次数:21

The Reaction of 2,3-Dimethylimidazole-1-sulfonyl Azide Triflate with 3-Substituted Indoles: Reactivity and Scope

Dr. Mei-Hua Shen,Ke Xu, Chu-Han Sun and Dr. Hua-Dong Xu

  

Article first published online: 07 JUL 2015 | DOI:10.1021/acs.orglett.5b01464

全文键连:http://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b01464?journalCode=orlef7&quickLinkVolume=17&quickLinkPage=3654&selectedTab=citation&volume=17

  

Abstract: 2,3-Dimethylimidazole-1-sulfonyl azide triflate reacts with 3-substituted indoles to deliver 2-iminoindolines, 2-aminoindoles, or 2-imino-3-aminoindolines by using different conditions. This imidazolium sulfonyl azide shows higher reactivity toward carbon nucleophile indoles than ordinary alkyl/aryl sulfonyl azides.